周恒辉 博士,副教授,博士生导师
分析化学,新能源材料
办公室:化学学院B106
电话:+86-10-62757908
电子信箱:hhzhou@pku.edu.cn
个人简历:
1999/12-至今,北大先行科技产业有限公司,首席科学家,教授级高工(2013)
2002/12-至今,北京大学,化学与分子工程学院,副教授,博士生导师
1998/09-2002/12,北京大学,化学与分子工程学院,讲师;
1995/09–1998/07,北京大学,化学与分子工程学院,博士研究生,导师:慈云祥教授;
1986/09–1989/07,湘潭大学,化学系,硕士研究生,导师:王应玮教授。
研究领域与兴趣:
1. 能量储存与转换材料的设计、合成及表征;
2. 化学能源中的电极/电解质界面研究;
3. 可移动能源器件的设计及其在3C电子产品、电动汽车中的应用。
近5年代表性论文:
1. Hu Y.R., Wu K., Zhang F., Zhou H.H. *, Qi L.M. *,Hierarchical MnO@C Hollow Nanospheres for Advanced Lithium-Ion Battery Anodes,ACS Appl. Nano Mater. 2019, 2:429−439
2. He, L., Chen, C., Kotobuki, M., Zheng, F., Zhou, H. *, Lu, L. *,A new approach for synthesizing bulk-type all-solid-state lithium-ion batteries, J. Mater. Chem. A, 2019,7 (16):9748-9760.
3. Zhang F., Yang C.K., Guan H.Q., Hu Y.R., Jin C., Zhou H.H.,* Qi L.M. *, 3D Copper Foam@FeOx Nanoarrays as A High Areal Capacity and Stable Electrode for Lithium-Ion Batteries, ACS Applied Energy Materials, 2018, 1(10):5417-5427
4. Wu K., Shi B.W., Qi L.Y., Mi Y.Y., Zhao B.L., Yang C.K., Wang Q., Tang H., Lu J., Liu W.,* Zhou H.H., * SnO2 quantum dots @ 3D sulfur-doped reduced graphene oxides as active and durable anode for lithium ion batteries,Electrochimica Acta, 2018,291:24-30
5. Wang S., Liu X., Wang A.L., Wang Z., Chen J., Zeng Q., Jiang X., Zhou H.H.,∗ Zhang L.Y.,∗ High-Performance All-Solid-State Polymer Electrolyte with Controllable Conductivity Pathway Formed by Self-Assembly of Reactive Discogen and Immobilized via a Facile Photopolymerization for a Lithium-Ion Battery,ACS Applied Materials and Interfaces,2018, 10(30): 25273-25284
6. Wang S., WangA.L., Yang C.K., Gao R., Liu X., Chen J., Wang Z.N., Zeng Q.H., Liu X.H., Zhou H.H.,∗ Zhang L.Y.,∗ Six-arm star polymer based on discotic liquid crystal as high performance all-solid-state polymer electrolyte for lithium-ion batteries,J. Power Sources, 2018, 395:137-147.
7. Wang Q. †, Yang C.K.†,Yang J.J., Wu K., Qi L.Y.,Tang H., Zhang Z.Y.,Liu W. *, Zhou H.H. *,Stable Li metal anode with protected interface for high-performance Li metal batteries, Energy Storage Materials ,2018,15: 249–256
8. Yang C.K.†, Shao R.W., Mia Y.Y., Shen L.Y., Zhao B.L.,Wang Q., Wu K., LiuW.*, Gao P.,* Zhou H.H. *,Stable interstitial layer to alleviate fatigue fracture of high nickel cathode,J. Power Sources, 2018, 376:200-206.
9. Zheng X.Y. †, Yang C.K.†,Zheng J. *,Zhou H.H.,*Li X.G.*,Synergism of rare earth trihydrides and graphite in lithium storage: evidence of hydrogen enhanced lithiation,Adv. Mater.,2018,30(3):1704353
10. Tu J.G., Wu K., Tang H.,Zhou H.H.,*, Jiao S.Q.,*Mg-Ti co-doping behavior of porous LiFePO4 microspheres for high-rate lithium-ion batteries,J. Mater. Chem. A, 2017, 5:17021-17028
11. Zhang F., Yang C.K., GaoX. , Chen S., Hu Y.R., Guan H.Q., Ma Y.R., Zhang J., Zhou H.H.*, Qi L.M.*,SnO2@PANI Core-Shell Nanorod Arrays on 3D Graphite Foam: A High-Performance Integrated Electrode for Lithium-Ion Batteries,ACS Appl. Mater. Interfaces, 2017,9(11): 9620-9629
12. Li G.Y., Zhang Z.J. *, Huang Z.L.,Yang C.K.,Zuo Z.C.,Zhou H.H.*,Understanding the accumulated cycle capacity fade caused by secondary particles fracture of LiNi1-x-yCoxMnyO2 cathode for lithium ion batteries,J.Solid State Electrochem., 2017,21(3): 673-682
13. Liu W., Jiang J.B., Yang K. R., Mi Y.Y., Kumaravadivel P., Zhong Y.R., Fan Q., Weng Z., Wu Z.S., Cha J.J., Zhou H.H., Batista V. S. *, Brudvig G.W. *, Wang H.L. *, An Ultrathin Dendrimer-Graphene Oxide Composite Film for Stable Cycling Lithium-Sulfur Batteries,PANS, 2017,114(14): 3578-3583
14. Mi Y.Y., Liu W., Yang K. R., Jiang J.B., Fan Q., Weng Z., Zhong Y.R., Wu Z.S., Brudvig G.W., Batista V. S. *, Zhou H.H.*, Wang H.L.*,Ferrocene Promoted Long Cycle Lithium-Sulfur Batteries,Angew. Chem. Int. Ed.,2016,55(47):14818-14822
15. Yang C.K., Qi L.Y., Zuo Z.C., Wang R.N., Ye M., Lu J., Zhou H.H. *, Insights into the Inner Structure of High-Nickel Agglomerate as High-Performance Lithium-Ion Cathodes,J. Power Sources, 2016, 331: 487-494
16. Li G.Y., Zhang Z.J. *,Wang R.N. *, Huang Z.L., Zuo Z.C.,Zhou H.H.*,Effect of Trace Al Surface Doping on the Structure, Surface Chemistry and Low Temperature Performance of LiNi0.5Co0.2Mn0.3O2 Cathode, Electrochimica Acta, 2016, 212:399-407
17. Qi L.Y., Xin Y.L., Zuo Z.C., Yang C.K., Wu K.,Wu B.,Zhou H.H.*,Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage,ACS Appl. Mater. Interfaces,2016,8(27):17245-17252
18. Qi L.Y., Zhang Y.W., Zuo Z.C., Xin Y.L.,Yang C.K.,Wu B., Zhang X.X.,Zhou H.H.*,In-situ Quantization of Ferroferric Oxide Embedded in Micro 3D Carbon for Ultrahigh Performance Sodium-Ion Battery,J. Mater. Chem. A,2016, 4:8822-8829
19. Yang X.H., J.G. Tu, M. Lei, Zuo Z.C., Wu B.R.,*Zhou H.H.*, Selection of Carbon Sources for Enhancing 3D Conductivity in the Secondary Structure of LiFePO4/C Cathode, Electrochimica Acta, 2016, 193:206-215
20. Fan X.Y., Li S.H.,Zhou H.H. *, Lu L. *,One-pot high temperature hydrothermal synthesis of Fe3O4@C/graphene nanocomposite as anode for high rate lithium ion battery,Electrochimica Acta, 2015, 180: 1041-1049
21. Xin Y.L.,Qi L.Y., Zhang Y.W., Zuo Z.C.*,Zhou H.H.*,Zhang X.X., Organic-Solvent Assisted Free-Standing Li2MnO3•LiNi1/3Co1/3Mn1/3O2 on 3D Graphene for High Energy Density Cathode, Chem. Commun., 2015, 51:16381-16384
22. Chen S, Xin Y.L., Zhou Y.Y., Zhang F., Ma Y.R., Zhou H.H. *, Qi L.M. *,Rational fabrication of robust α-Fe2O3 nanorod arrays with optimized internal pores for high-performance lithium ion batteries, J. Mater. Chem. A,2015, 3:13377 - 13383
23. Yang X.H., Zuo Z.C.,Wu B.,Huang Z.L.,Chen Q.B., Zhang H.,Wu B.R.,*Zhou H.H.*, The Contradiction Between the Half-Cell and Full-Battery Evaluations on the Tungsten-Coating LiNi0.5Co0.2Mn0.3O2 Cathode, Electrochimica Acta, 2015, 180:604-609
24. Mi Y.Y., Yang C.K.,Qi L.Y., Tang C.X., Zhang W.D. *,Zhou H.H. *,Remarkable Effect of Minor Manganese-doping on LiFePO4/C for Improved Cathode Materials in Lithium-ion Batteries, Electrochimica Acta, 2015, 176:642-648
25. Qi L.Y., Zhang Y.W., Xin Y.L., Zuo Z.C., Wu B.,* Zhang X.X.,Zhou H.H.*,Rolling-Reprocess Fabrication of Olive-Like Fe−Co−O Nanoparticles@3D N-doped Reduced Graphene Oxide for High Performance Lithium Battery,Nanoscale, 2015,7: 7841-7848
26. Yang X.H., Shen L.Y., Wu B., Zuo Z.C., Mu D.B., Wu B.R.,*Zhou H.H.*,Improvement of the cycling performance of LiCoO2with assistance of cross-linked PAN for lithium ion batteries, Journal of Alloys and Compounds,2015, 639:458-464.
27. Li G.Y., Huang Z.L., Zuo Z.C.,Zhang Z.J. *,Zhou H.H.*,Understanding the Trace Ti Surface Doping on Promoting the Low Temperature Performance of LiNi1/3Co1/3Mn1/3O2 Cathode,J. Power Sources, 2015,281: 69-76.
28. Yang X.H. ‡,Mi Y.Y. ‡, Zhang W.D., WuB.R. *, Zhou H.H.*, Enhanced Electrochemical Performance of LiFe0.6Mn0.4PO4/C Cathode Material Prepared by Ferrocene-Assisted Calcination Process,J. Power Sources, 2015, 275:823-830.
Curriculum Vitae
Henghui Zhou,Ph. D. Associate Professor
Analytical Chemistry, Advanced energy materials
Office:B106, College of Chemistry and Molecular Engineering
Tel:+86-10-62757908
E-mail:hhzhou@pku.edu.cn
Vita:
1999/12-present,Pulead Technology Industry Co.,Ltd,Chief Scientist,Prefessor
2002/12-present, College of Chemistry and Molecular Engineering,Peking University, Associate Professor
1998/09-2002/12, College of Chemistry and Molecular Engineering,Peking University, Lecturer
1995/09–1998/07, Ph. D.,College of Chemistry and Molecular Engineering,Peking University, Advisor: Prof. Yunxiang Ci
1986/09–1989/07, B. S., Department of Chemistry, Xiangtan University, Advisor: Prof. Yingwei Wang
Research fields and interests
1. Design, synthesis and characterization of energy storage and conversion materials;
2. Interfaces between electrode and electrolyte in chemical power systems;
3. Design of portable energy devices and their applications in 3C electronic products and electric vehicles.
Selected Publications
1. Hu Y.R., Wu K., Zhang F., Zhou H.H. *, Qi L.M. *,Hierarchical MnO@C Hollow Nanospheres for Advanced Lithium-Ion Battery Anodes,ACS Appl. Nano Mater. ,2019, 2:429−439
2. He, L., Chen, C., Kotobuki, M., Zheng, F., Zhou, H. *, Lu, L. *,A new approach for synthesizing bulk-type all-solid-state lithium-ion batteries, J. Mater. Chem. A, 2019,7 (16):9748-9760.
3. Zhang F., Yang C.K., Guan H.Q., Hu Y.R., Jin C., Zhou H.H.,* Qi L.M. *, 3D Copper Foam@FeOx Nanoarrays as A High Areal Capacity and Stable Electrode for Lithium-Ion Batteries, ACS Applied Energy Materials, 2018, 1(10):5417-5427
4. Wu K., Shi B.W., Qi L.Y., Mi Y.Y., Zhao B.L., Yang C.K., Wang Q., Tang H., Lu J., Liu W.,* Zhou H.H., * SnO2 quantum dots @ 3D sulfur-doped reduced graphene oxides as active and durable anode for lithium ion batteries,Electrochimica Acta, 2018,291:24-30
5. Wang S., Liu X., Wang A.L., Wang Z., Chen J., Zeng Q., Jiang X., Zhou H.H.,∗ Zhang L.Y.,∗ High-Performance All-Solid-State Polymer Electrolyte with Controllable Conductivity Pathway Formed by Self-Assembly of Reactive Discogen and Immobilized via a Facile Photopolymerization for a Lithium-Ion Battery,ACS Applied Materials and Interfaces,2018, 10(30): 25273-25284
6. Wang S., WangA.L., Yang C.K., Gao R., Liu X., Chen J., Wang Z.N., Zeng Q.H., Liu X.H., Zhou H.H.,∗ Zhang L.Y.,∗ Six-arm star polymer based on discotic liquid crystal as high performance all-solid-state polymer electrolyte for lithium-ion batteries,J. Power Sources, 2018, 395:137-147.
7. Wang Q. †, Yang C.K.†,Yang J.J., Wu K., Qi L.Y.,Tang H., Zhang Z.Y.,Liu W. *, Zhou H.H. *,Stable Li metal anode with protected interface for high-performance Li metal batteries, Energy Storage Materials ,2018,15: 249–256
8. Yang C.K.†, Shao R.W., Mia Y.Y., Shen L.Y., Zhao B.L.,Wang Q., Wu K., LiuW.*, Gao P.,* Zhou H.H. *,Stable interstitial layer to alleviate fatigue fracture of high nickel cathode,J. Power Sources, 2018, 376:200-206.
9. Zheng X.Y. †, Yang C.K.†,Zheng J. *,Zhou H.H.,*Li X.G.*,Synergism of rare earth trihydrides and graphite in lithium storage: evidence of hydrogen enhanced lithiation,Adv. Mater.,2018,30(3):1704353
10. Tu J.G., Wu K., Tang H.,Zhou H.H.,*, Jiao S.Q.,*Mg-Ti co-doping behavior of porous LiFePO4 microspheres for high-rate lithium-ion batteries,J. Mater. Chem. A, 2017, 5:17021-17028
11. Zhang F., Yang C.K., GaoX. , Chen S., Hu Y.R., Guan H.Q., Ma Y.R., Zhang J., Zhou H.H.*, Qi L.M.*,SnO2@PANI Core-Shell Nanorod Arrays on 3D Graphite Foam: A High-Performance Integrated Electrode for Lithium-Ion Batteries,ACS Appl. Mater. Interfaces, 2017,9(11): 9620-9629
12. Li G.Y., Zhang Z.J. *, Huang Z.L.,Yang C.K.,Zuo Z.C.,Zhou H.H.*,Understanding the accumulated cycle capacity fade caused by secondary particles fracture of LiNi1-x-yCoxMnyO2 cathode for lithium ion batteries,J.Solid State Electrochem., 2017,21(3): 673-682
13. Liu W., Jiang J.B., Yang K. R., Mi Y.Y., Kumaravadivel P., Zhong Y.R., Fan Q., Weng Z., Wu Z.S., Cha J.J., Zhou H.H., Batista V. S. *, Brudvig G.W. *, Wang H.L. *, An Ultrathin Dendrimer-Graphene Oxide Composite Film for Stable Cycling Lithium-Sulfur Batteries,PANS, 2017,114(14): 3578-3583
14. Mi Y.Y., Liu W., Yang K. R., Jiang J.B., Fan Q., Weng Z., Zhong Y.R., Wu Z.S., Brudvig G.W., Batista V. S. *, Zhou H.H.*, Wang H.L.*,Ferrocene Promoted Long Cycle Lithium-Sulfur Batteries,Angew. Chem. Int. Ed.,2016,55(47):14818-14822
15. Yang C.K., Qi L.Y., Zuo Z.C., Wang R.N., Ye M., Lu J., Zhou H.H. *, Insights into the Inner Structure of High-Nickel Agglomerate as High-Performance Lithium-Ion Cathodes,J. Power Sources, 2016, 331: 487-494
16. Li G.Y., Zhang Z.J. *,Wang R.N. *, Huang Z.L., Zuo Z.C.,Zhou H.H.*,Effect of Trace Al Surface Doping on the Structure, Surface Chemistry and Low Temperature Performance of LiNi0.5Co0.2Mn0.3O2 Cathode, Electrochimica Acta, 2016, 212:399-407
17. Qi L.Y., Xin Y.L., Zuo Z.C., Yang C.K., Wu K.,Wu B.,Zhou H.H.*,Grape-Like Fe3O4 Agglomerates Grown on Graphene Nanosheets for Ultrafast and Stable Lithium Storage,ACS Appl. Mater. Interfaces,2016,8(27):17245-17252
18. Qi L.Y., Zhang Y.W., Zuo Z.C., Xin Y.L.,Yang C.K.,Wu B., Zhang X.X.,Zhou H.H.*,In-situ Quantization of Ferroferric Oxide Embedded in Micro 3D Carbon for Ultrahigh Performance Sodium-Ion Battery,J. Mater. Chem. A,2016, 4:8822-8829
19. Yang X.H., J.G. Tu, M. Lei, Zuo Z.C., Wu B.R.,*Zhou H.H.*, Selection of Carbon Sources for Enhancing 3D Conductivity in the Secondary Structure of LiFePO4/C Cathode, Electrochimica Acta, 2016, 193:206-215
20. Fan X.Y., Li S.H.,Zhou H.H. *, Lu L. *,One-pot high temperature hydrothermal synthesis of Fe3O4@C/graphene nanocomposite as anode for high rate lithium ion battery,Electrochimica Acta, 2015, 180: 1041-1049
21. Xin Y.L.,Qi L.Y., Zhang Y.W., Zuo Z.C.*,Zhou H.H.*,Zhang X.X., Organic-Solvent Assisted Free-Standing Li2MnO3•LiNi1/3Co1/3Mn1/3O2 on 3D Graphene for High Energy Density Cathode, Chem. Commun., 2015, 51:16381-16384
22. Chen S, Xin Y.L., Zhou Y.Y., Zhang F., Ma Y.R., Zhou H.H. *, Qi L.M. *,Rational fabrication of robust α-Fe2O3 nanorod arrays with optimized internal pores for high-performance lithium ion batteries, J. Mater. Chem. A,2015, 3:13377 - 13383
23. Yang X.H., Zuo Z.C.,Wu B.,Huang Z.L.,Chen Q.B., Zhang H.,Wu B.R.,*Zhou H.H.*, The Contradiction Between the Half-Cell and Full-Battery Evaluations on the Tungsten-Coating LiNi0.5Co0.2Mn0.3O2 Cathode, Electrochimica Acta, 2015, 180:604-609
24. Mi Y.Y., Yang C.K.,Qi L.Y., Tang C.X., Zhang W.D. *,Zhou H.H. *,Remarkable Effect of Minor Manganese-doping on LiFePO4/C for Improved Cathode Materials in Lithium-ion Batteries, Electrochimica Acta, 2015, 176:642-648
25. Qi L.Y., Zhang Y.W., Xin Y.L., Zuo Z.C., Wu B.,* Zhang X.X.,Zhou H.H.*,Rolling-Reprocess Fabrication of Olive-Like Fe−Co−O Nanoparticles@3D N-doped Reduced Graphene Oxide for High Performance Lithium Battery,Nanoscale, 2015,7: 7841-7848
26. Yang X.H., Shen L.Y., Wu B., Zuo Z.C., Mu D.B., Wu B.R.,*Zhou H.H.*,Improvement of the cycling performance of LiCoO2with assistance of cross-linked PAN for lithium ion batteries, Journal of Alloys and Compounds,2015, 639:458-464.
27. Li G.Y., Huang Z.L., Zuo Z.C.,Zhang Z.J. *,Zhou H.H.*,Understanding the Trace Ti Surface Doping on Promoting the Low Temperature Performance of LiNi1/3Co1/3Mn1/3O2 Cathode,J. Power Sources, 2015,281: 69-76.
28. Yang X.H. ‡,Mi Y.Y. ‡, Zhang W.D., WuB.R. *, Zhou H.H.*, Enhanced Electrochemical Performance of LiFe0.6Mn0.4PO4/C Cathode Material Prepared by Ferrocene-Assisted Calcination Process,J. Power Sources, 2015, 275:823-830.